4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Names and Identifiers

Name	Tosylmethyl isocyanide
Synonyms	Tosmic Tosylmethyl isocyani Tosylmethylisocyanide Tosylmethyl isocyanide Labotest-Bb Lt00159629 4-Toluenesulfonylmethylisocyanide P-Toluenesulfonylmethyl Isocyande Toluenesulfonyl Methyl isocyanide 4-Toluensulfonylmethyl Isocyanide (P-Tolylsulfonyl)Methyl Isocyanide P-Toluenesulfonyl Methylisocyanide P-Toluenesulfonylmethyl Isocyanide (p-Toluensulfonyl)methylisocyanide 4-Toluenesulfonylmethyl Isocyanide 4-Toluenesulphonylmethyl Isocyanide Isocyanomethyl 4-methylphenyl sulphone [(4-Methylphenyl)Sulfonyl]Acetonitrile 1-[(Isocyanomethyl)Sulfonyl]-4-Methyl-Benzen 1-[(isocyanomethyl)sulfonyl]-4-methyl-benzen 1-[(Isocyanomethyl)Sulfonyl]-4-Methylbenzene Benzene, 1-[(Isocyanomethyl)Sulfonyl]-4-Methyl- Methylidyne[[(4-Methylphenyl)Sulfonyl]Methyl]Ammonium (p-Tolylsulfonyl)methyl isocyanide, TosMIC, Tosylmethyl isocyanide 4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide
CAS	36635-61-7
EINECS	253-140-1
InChI	InChI=1/C9H9NO2S/c1-8-3-5-9(6-4-8)13(11,12)7-10-2/h3-6H,7H2,1H3
InChIKey	BBNNLJMGPASZPD-UHFFFAOYSA-N

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Physico-chemical Properties

Molecular Formula	C9H9NO2S
Molar Mass	195.24
Density	1.2721 (rough estimate)
Melting Point	109-113°C(lit.)
Water Solubility	insoluble
Solubility	water: slightly soluble
Appearance	Yellow to brown crystals
Color	Clear
Exposure Limit	NIOSH: IDLH 25 mg/m3
Merck	14,9556
BRN	3592382
Storage Condition	2-8°C
Sensitive	Moisture Sensitive
Refractive Index	1.5270 (estimate)
MDL	MFCD00000005
Physical and Chemical Properties	Melting point 110-115°C water-soluble insoluble

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Risk and Safety

Risk Codes	23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
Safety Description	S36/37 - Wear suitable protective clothing and gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S38 - In case of insufficient ventilation, wear suitable respiratory equipment. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S28A -
UN IDs	UN 2811 6.1/PG 3
WGK Germany	3
FLUKA BRAND F CODES	21
HS Code	29299000
Hazard Note	Irritant
Hazard Class	6.1(b)
Packing Group	III

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Reference Information

Uses

p-methylbenzenesulfonylisonitrile is used as a synthetic reagent to prepare various or biologically active heterocyclic rings, such as pyrrole and imidazole. It is reported that toluene sulfonyl methyl isocyanide inhibits [Fe]-hydrogenase with high efficiency.
Reagents used to prepare biologically active pyrrole and imidazole; as isonitrile components, used in stereoselective Passerini reactions containing carbohydrate-derived aldehydes

Last Update：2024-04-09 15:16:50

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide

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4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide

Tosylmethyl isocyanide

CAS: 36635-61-7

Molecular Formula: C9H9NO2S

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Names and Identifiers

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Physico-chemical Properties

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Risk and Safety

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Reference Information

Supplier List

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide Request for Quotation

Tosylmethyl isocyanide

CAS: 36635-61-7

Molecular Formula: C9H9NO2S

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Names and Identifiers

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Physico-chemical Properties

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Risk and Safety

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide - Reference Information

Supplier List

4-[(Isocyanomethyl)sulphonyl]toluene, (Toluene-4-sulphonyl)methyl isocyanide